硬化時間決定成敗!環氧樹脂施工前你必須知道的事

Epoxy resin is widely used in flooring coatings, structural reinforcement, electronic encapsulation, and crafts. For beginners, one of the most common issues is misjudging the curing time, which can lead to failed applications, sticky surfaces, bubbles, or even complete batch rejection. This article introduces four commonly overlooked technical concepts to help you prepare properly before application and avoid costly mistakes.

Hardener ≠ Catalyst: Stop Mixing Them Up!

Many beginners mistakenly think that a “hardener” is the same as a “catalyst,” but these two play very different roles in chemical reactions.

  • Hardener is part of the reaction: In epoxy systems, the hardener (often amine-based) reacts with the base resin to form a crosslinked network. This reaction is irreversible, and the ratio of hardener directly affects the final performance.
  • Catalyst only accelerates the reaction: A catalyst does not participate in the reaction itself. It simply speeds up the curing process and, theoretically, is not consumed or affects hardness.

🔧 Practical Tip:
Never adjust the hardener ratio arbitrarily. Too much can cause a sticky surface; too little may result in incomplete curing. Always follow the product’s recommended ratio (e.g., A:B = 2:1 or 1:1) and measure accurately.

 

Pot Life vs. Mixing Volume: Beware of Solvent Entrapment

“Why does my resin harden before I can finish using it, even though I mixed it correctly?” This is usually due to ignoring the relationship between pot life and volume.

  • Pot Life: The workable time after mixing, during which the resin remains fluid and usable.
  • Larger volume = faster reaction: Epoxy curing is an exothermic reaction. The more you mix at once, the more heat is generated and retained, which accelerates the reaction and shortens pot life.

What Is Solvent Entrapment?

When mixing volume is too large or the container is too deep, the heat generated can prevent residual solvents (e.g., thinners or additives) from evaporating properly. These solvents become trapped inside the resin—this is known as solvent entrapment. It can lead to:

    • Sticky or hazy surface
    • Uneven curing or internal bubbles
    • Reduced adhesion, affecting subsequent coatings or bonding

📌 Example:
If a product specifies “Pot Life = 30 minutes (100g at 25°C)” and you mix 500g in one container, your actual working time may drop below 10 minutes—and solvent entrapment becomes much more likely.

🧪 Recommended Practices:

    • Mix in smaller batches to avoid excessive heat buildup; control application thickness and ensure good ventilation.
    • Use shallow or flat containers to spread out the mixture, aiding heat dissipation and solvent evaporation.
    • Avoid leaving mixed resin in sealed containers for extended periods.

溶劑滯留

How Humidity and Air Conditioning Affect Curing Time

While epoxy resin is not as moisture-sensitive as polyurethane, humidity and air-conditioned environments still significantly affect curing quality and timing.

🌧️ Effects of High Humidity:

    • May cause “amine blush”: a whitish or greasy residue on the surface, affecting adhesion and appearance.
    • Slows down the curing reaction, possibly leading to incomplete curing.

❄️ Effects of Air Conditioning:

    • Low temperatures (below 20°C) in air-conditioned rooms can delay the reaction and extend curing time.
    • Strong dehumidification helps stabilize the curing process.

🛠️ Application Tips:

    • Ideal working conditions: temperature at 25°C ±2°C, humidity below 70%.
    • In humid weather, use a dehumidifier or work in a sealed space with air conditioning.
    • If amine blush appears after curing, wipe the surface with alcohol before proceeding with the next layer.

Stirring Speed and Technique: Don’t Let Bubbles Ruin Your Work

Stirring may seem simple, but it’s a critical factor in curing quality. Stirring too fast or improperly can introduce bubbles, cause uneven mixing, or even lead to curing failure.

⚙️ Effects of Stirring Speed:

    • Too fast: Introduces excessive bubbles, especially problematic in clear resin or encapsulation applications.
    • Too slow: Results in uneven mixing, leading to localized curing issues or sticky surfaces.

🌀 Proper Stirring Method (for mixing a 20kg drum of epoxy resin):

    • Use a low-speed mixer (300–600 rpm) with steady rotation.
    • Stir for about 3–5 minutes, ensuring thorough mixing at the edges and bottom.
    • For high-viscosity or filler-loaded formulas, extend stirring time to ensure even dispersion.
    • Let the mixture sit for 1–2 minutes after stirring to allow bubbles to rise naturally.

💡 Practical Tips:

    • If bubbles are a concern, use a vacuum degassing machine or heat gun to assist bubble removal.
    • Use flat or spiral mixing paddles; avoid thin rods that create dead zones.

Conclusion: Master the Details to Master the Quality

Curing time in epoxy resin isn’t just about waiting—it’s the key to success or failure. From understanding the role of hardeners, controlling mixing volume, adjusting environmental conditions, to mastering stirring techniques, every detail affects the final product’s quality and consistency.

For beginners, stability is more important than speed. Once you grasp these essential concepts and techniques, epoxy resin will no longer be a difficult material to handle—it will become your reliable partner in creation and construction.

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